Determination of Organotin Compounds in Polyvinyl Chloride Toys
نویسندگان
چکیده
منابع مشابه
[Determination of organotin compounds in polyvinyl chloride toys].
Organotin compounds in polyvinyl chloride toys were determined by GC/MS after ethyl derivatization with sodium tetraethylborate. The samples were 12 balls, 12 soft toys, 10 food toys and 13 face masks for children. Monooctyltin, dioctyltin and trioctyltin compounds were found in all face masks at the levels of 74.8-917 micrograms/g. 474-3,960 micrograms/g and 1.0-213 micrograms/g, respectively....
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Plasticizers in 101 samples of polyvinyl chloride (PVC) toys on the Japanese market were surveyed. No phthalates were detected in designated toys, though bis(2-ethylhexyl)phthalate, diisononyl phthalate, diisobutyl phthalate, dibutyl phthalate, diisodecyl phthalate and benzyl butyl phthalate were detected in more than half of other toys. 2,2,4-Tributyl-1,3-pentanediol diisobutylate, o-acetyl tr...
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A simple and rapid method using HPLC was developed for the determination of tricresyl phosphate (TCP) in polyvinyl chloride (PVC) articles. A test sample was extracted with acetonitrile at 37 degrees C overnight. The extract solution diluted with an equivalent amount of water was applied to a Sep-Pak C18 cartridge, and TCP was eluted with acetonitrile-water (2:1) mixture. The eluate was analyze...
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Organotin compound that have at least one Sn-C bond have wide commercial applications as PVC stabilizer, antifouling agent in paint and as agrochemicals. The general formula for organotin compounds is R4SnX4 - n where R is normally alkyl or aryl groups and X=Cl-, OH-, CH3COO- . If n=3, the compound has the highest toxicity, for example Et3SnOAC has LD 50 4mg/Kg ( rats ) and this is the m...
متن کاملThermal Degradation of Polyvinyl Chloride
A survey is given of the recent advances in the study of and the present knowledge of the thermal degradation of polyvinyl chloride. The sites for initiation of the thermal degradation, the mechanism of the dehydrochiorination, the discolouration of PVC by heat and the influence of plasticizers on the rate of degradation are discussed.
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ژورنال
عنوان ژورنال: Journal of the Food Hygienic Society of Japan (Shokuhin Eiseigaku Zasshi)
سال: 2003
ISSN: 0015-6426,1882-1006
DOI: 10.3358/shokueishi.44.208